Crystal structure of methyl 2-(2-chloroacetyl)-1-(4-(methoxycarbonyl)phenyl)-2,3,4,9-tetrahydro-1<i>H</i>-pyrido[3,4-<i>b</i>] indole-3-carboxylate, C<sub>23</sub>H<sub>21</sub>ClN<sub>2</sub>O<sub>5</sub>
نویسندگان
چکیده
Abstract C 23 H 21 ClN 2 O 5 , monoclinic, P 1 / c (no. 14), a = 9.191(3) Å, b 10.725(5) 11.2390(10) β 109.869(13)°, V 1041.9(6) Å 3 Z 2, R gt ( F ) 0.0609, wR ref 0.1695, T 293 K.
منابع مشابه
Crystal structure of (E)-2-(4-methoxystyryl)-3-methyl-1-phenylsulfonyl-1H-indole
In the title compound, C24H21NO3S, the dihedral angles between the indole ring system (r.m.s. deviation = 0.030 Å) and the sulfur and ethyl-ene-bonded benzene rings are 80.2 (2) and 49.29 (15)°, respectively. The dihedral angle between the pendant benzene rings is 37.7 (2)°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds and weak C-H⋯π and π-π [centroid-to-centroid distances = 3....
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In the title indole derivatives, C22H16N2O5S, (I) and C20H15NO3S2, (II), the sulfonyl-bound phenyl rings are almost orthogonal to the indole ring system, subtending dihedral angles of 88.33 (10) and 87.58 (16)°, respectively. In both compounds, the sulfonyl S atom has a distorted tetra-hedral geometry [O-S-O = 119.98 (9) and N-S-C = 104.01 (8)° for compound (I) and O-S-O = 120.08 (18) and N-S-C...
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In the title compound, C(10)H(12)N(2)S, the thio-phene ring is essentially planar (r.m.s. deviation = 0.0290 Å). The two C atoms of the cyclo-hexene ring (at positions 6 and 7) are disordered over two sets of sites in a 0.810 (5):0.190 (5) ratio. The cyclo-hexene rings in both the major and minor occupancy conformers adopt a half-chair conformation. In the crystal, there are two types of N-H⋯N ...
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The indole N-H hydrogen in the title compound, C(15)H(12)FN, does not display classical hydrogen bonding. Rather it forms an interaction with the π system of an adjacent indole, resulting in weakly inter-acting chains along the [001] direction.
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ژورنال
عنوان ژورنال: Zeitschrift Fur Kristallographie-new Crystal Structures
سال: 2023
ISSN: ['2197-4578', '1433-7266']
DOI: https://doi.org/10.1515/ncrs-2022-0579